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| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Grand Ballroom |
| Time |
10월 18일 (목요일) 11:00~12:30 |
| Code |
MAT.P-369 |
| Subject |
Metal-ion Tuning in Amine-Functionalized Supramolecular Triple-Stranded Helicates and Their Higher-Order Polymeic Assemblies |
| Authors |
Van Cam Thi Le, Philjae Kang1, Hien Duy Mai1, Hyojong Yoo1,*
Chemistry, Hallym University, Korea
1Department of Chemistry, Hallym University, Korea
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| Abstract |
With respect to the design of metallosupramolecules, the choice of metal ions is of considerable importance for the targeted crystal structures. Herein, we report a strategy to achieve isostructural amine-functionalized supramolecules containing different transition metals (cobalt, nickel, and manganese), namely, M8(PDA)6(AIP)3(DMF)6, where M = Co (1), Ni (2), and Mn (3) (PDA = 2,6-pyridinedicarboxylate, AIP = 5-aminoisophthalate, DMF = dimethylformamide). The variation in the transition metal ions used negligibly affects the coordinative assembly of metal and ligand species, suggesting a high degree of symmetry and stability of triple-stranded helical conformations. In addition, the change in metal ions can lead to distinctive physical or chemical properties of the resultant TSHs. In addition, 1, 2, and 3 can be employed as conceptual supramolecular modules for the construction of higher-order polymeric structures via the coordination with extra metal ions. |
| E-mail |
lethicamvan@gmail.com |
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122nd General Meeting of the KCS