122nd General Meeting of the KCS

Type Symposium
Area Current Trends in Organic Chemistry II: Synthetic Methology and Catalysis
Room No. Room 325A+B
Time FRI 09:25-:
Code ORGN2-2
Subject Visible-light-induced radical reactions: Applications in the synthesis of bioactive molecules
Authors Anna Lee
Department of Chemistry, Myongji University, Korea
Abstract Recently, visible-light-mediated photoredox catalysis has emerged as a powerful tool in organic synthesis.1 Transition metal-based photocatalysts such as ruthenium and iridium polypyridyl complexes are widely employed in photoredox catalysis with great reported success. However, based on the limitations of utilizing transition metals, the development of green activation modes in photoredox system is very important. In this presentation, I will present recent work on organo-photocatalysis and photocatalyst-free reactions and their applications in the synthesis of bioactive molecules.2 1. (a) K. Zeitler, Angew. Chem. Int. Ed. 2009, 48, 9785. (b) T. P. Yoon; M. A. Ischay; J. Du, Nature Chem. 2010, 2, 527. (c) J. M. R. Narayanam; C.R. J. Stephenson, Chem. Soc. Rev. 2011, 40, 102. (d) L. Shi; W. Xia, Chem. Soc. Rev. 2012, 41, 7687. (e) J. W. Tucker; C. R. J. Stephenson, J. Org. Chem. 2012, 77, 1617. 2. (a) B. Hong; J. Lee; A. Lee, Tetrahedron Lett. 2017, 58, 2809. (b) D. H. Kim; J. Lee; A. Lee, Org. Lett. 2018, 20, 764.
E-mail annalee@mju.ac.kr