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| Type |
Oral Presentation |
| Area |
Oral Presentation of Young Inorganic Chemists |
| Room No. |
Room 401+402 |
| Time |
THU 10:50-11:00 |
| Code |
INOR.O-12 |
| Subject |
Structure and Reactivity of a Mononuclear Nonheme Manganese(III)-Iodosylarene Complex |
| Authors |
Donghyun Jeong, Jaeheung Cho*
Emerging Materials Science, DGIST, Korea
|
| Abstract |
Transition metal-iodosylarene complexes have been proposed to be key intermediates in the catalytic cycles of metal catalysts with iodosylarene. We report the first X-ray crystal structure and spec-troscopic characterization of a mononuclear nonheme manganese(III)-iodosylarene complex with a tetradentate macrocyclic ligand, [MnIII(TBDAP)(OIPh)(OH)]2+ (2). The manganese(III)-iodosylarene complex is capable of conducting various oxidation reactions with organic substrates, such as C-H bond activation, sulfoxidation and epoxidation. Kinetic studies includ-ing isotope labeling experiments and Hammett correlation demonstrate the electrophilic character on the Mn-iodosylarene adduct. This novel intermediate would be prominently valuable for expanding the chemistry of transition metal catalysts. |
| E-mail |
carier4@dgist.ac.kr |
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123rd General Meeting of the KCS