|
|
| Type |
Poster Presentation |
| Area |
Organic Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 18일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-171 |
| Subject |
Metal-free Formylation of Amines |
| Authors |
Seul Chan Lee, Hye-Young Jang1,*
Department of Energy System, Ajou University, Korea
1Department of Chemistry, Ajou University, Korea
|
| Abstract |
To develop sustainable and environmentally-friendly technologies, utilization of greenhouse gases like carbon monoxide(CO), carbon dioxide(CO2) and methane(CH4) has been studied widely.
A variety of processes using these gases have been investigated and commercialized, in particular, carbonylation using carbon monoxide(CO) has also been employed in commercial processes for producing chemical products. For example, Fischer-Tropsch process, acetic acid synthesis, and hydroformylation are known.
Most of carbonylation processes require expensive transition metal catalysts like iridium, rhodium, cobalt, iron and nickel because CO is not reactive toward organic compounds.
In this study, we focused on the formylation of amines using CO in the absence of metal catalysts.
Detailed reaction conditions and results are discussed.
|
| E-mail |
tmfcks93@ajou.ac.kr |
|
123rd General Meeting of the KCS