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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 18일 (목요일) 11:00~12:30 |
| Code |
INOR.P-14 |
| Subject |
Synthesis and Structural Characterization of [(PPEA)MX2] (M = Co, Cu, X = Cl; M = Cd, X = Br) with the ligand (E)-2-(piperidin-1-yl)- N-(pyridin-2-ylmethylene)ethanamine |
| Authors |
Seongmin Kwon, Hyosun Lee*
Department of Chemistry, Kyungpook National University, Korea
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| Abstract |
We have synthesized a series of new cobalt(II), copper(II), and cadmium(II) complexes by the reaction of ligand (E)-2-(piperidin-1-yl)-N-(pyridin-2-ylmethylene)ethanamine (PPEA). Namely, [(PPEA)MX2] (M = Co, Cu, X = Cl; M = Cd, X = Br). These complexes were characterized by spectroscopic methods such as IR, 1H-NMR, 13C-NMR and elemental analyzer. Molecular structure of [(PPEA)CuCl2] and [(PPEA)CdBr2] were determined by single crystal X-ray diffraction. Specifically, both complexes were a distorted square pyramidal geometry around the metal centers. The catalytic properties of these complexes toward the polymerization of methyl methacrylate (MMA) in the presence of MMAO were also investigated at 60oC. |
| E-mail |
smk0503kr@naver.com |
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123rd General Meeting of the KCS