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| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 19일 (금요일) 11:00~12:30 |
| Code |
MAT.P-412 |
| Subject |
Asdorption removal of benzothiophene from liquid fuel with ionic liquid supported metalorganic framework |
| Authors |
JongMin Park, Sung Hwa Jhung*
Department of Chemistry, Kyungpook National University, Korea
|
| Abstract |
Sulfur containing compounds in liquid fuels are considered as the sources of the toxic SOx emmision. Therefore, there is a considerable demand to reduce those compounds from marketable fuels to a very low level to prevent air pollution and deactivation of catalysts. Metal-organic frameworks (MOFs) modified with the introduction of acidic ionic liquids (ILs) have been employed to the adsorptive removal of benzothiophene (BT) from n-octane. ILs were synthesized inside a porous MIL-101(Cr) via a ship-in-bottle (SIB) technique. The maximum adsorption capacities (Q0) for the virgin MIL-101(Cr) and for IL@MIL-101(Cr) were 49 and 68 mg/g, respectively, corresponding to a 37% increase in Q0. The Q0 value, based on the surface area (mg/m2) of the adsorbents, increased by 94% for ILs@MIL-101(Cr) (prepared via the SIB route), thus demonstrating the high affinity of ILs for BT. The improved adsorptive performance for BT might be derived from a specific interaction between the acidic ILs and the BT molecules. More importantly, unlike previously reported IL-incorporated MIL-101(Cr)s, IL@MIL-101(Cr) prepared by the SIB approach was very stable for adsorption of BT over several cycles. |
| E-mail |
pjm2669@naver.com |
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123rd General Meeting of the KCS