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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 18일 (목요일) 11:00~12:30 |
| Code |
INOR.P-21 |
| Subject |
Re(I) bridged self-assembled Sn(IV)porphyrin based metallacycles |
| Authors |
Nirmal Kumar Shee, Hee-Joon Kim1,*
Department of Applied chemistry, Kumoh National Institute of Technology, Korea
1Department of Applied Chemistry, Kumoh National Institute of Technology, Korea
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| Abstract |
Re(CO)5Cl readily reacts with 4-pyridyl-derivatized Sn(IV)porphyrins to give molecular squares featuring fac-Re(CO)3(Cl) corners. The 4 + 4 Re(I)–Sn(IV)porphyrin tetrads which has been fully characterized by means of FTIR, NMR, and UV-Vis (both absorption and emission) spectroscopies. The self-assembled Re(I)–metallacycles with Sn(IV)porphyrins are able to incorporate inside the cavity with different O-donor ligands that bind axially to the Sn(IV) ion. |
| E-mail |
nirmalshee@gmail.com |
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123rd General Meeting of the KCS