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|
| Type |
Poster Presentation |
| Area |
Polymer Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 19일 (금요일) 11:00~12:30 |
| Code |
POLY.P-5 |
| Subject |
Self-assembly of Chiral Amphiphilic Random Copolymer in Aqueous Media |
| Authors |
Minjoong Shin, Myungeun Seo*
Graduate School of Nano Science Technology, Korea Advanced Institute of Science and Technology, Korea
|
| Abstract |
Amphiphilic random copolymers containing hydrophobic and hydrophilic side chains spontaneously self-assemble in water via hydrophobic interaction into a spherical unimer or multi-chain micelles. We design amphiphilic random copolymers containing a stereocenter in the hydrophobic chain to investigate how molecular chirality can affect the micellar packing in aqueous solution. We synthesize two mirror-imaged hydrophobic monomers and incorporate into the amphiphilic random copolymer via reversible addition-fragmentation chain transfer (RAFT) process. Their chiral effects on self-assembly will be discussed based on the dynamic light scattering (DLS), circular dichroism spectroscopy (CD), and small angle X-ray scattering (SAXS) analyses. |
| E-mail |
mshin87@kaist.ac.kr |
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123rd General Meeting of the KCS