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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 18일 (목요일) 11:00~12:30 |
| Code |
INOR.P-26 |
| Subject |
Synthesis and properties of Ni(II), Pd(II), and Pt(II) complexes with five-membered heterocyclic rings |
| Authors |
Yong-Joo Kim*, Heekwon Park, MinGyu Ham, Soon W. Lee1
Department of Chemistry, Gangneung-Wonju National University, Korea
1Department of Chemistry, Sungkyunkwan University, Korea
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| Abstract |
Various Pd(II) and Pt(II) complexes having five-membered heterocyclic rings were obtained from the reactions of trans-PdEt2(PR3)2 or cis-PtEt2(PR3)2 with organic tetrazole-thiones {S=[C{HN4(R)}]. Independently, treatments of Pd(N3)2L2 or Ni(N3)2(L2) with organic (R-N=C=S) or isocyanide (R-N≡C) afforded corresponding Pd(II) or Ni(II) complexes having heterocyclic rings or carodiimide complexes (M-N=C=N-R). The isolated complexes were determined by IR and NMR spectroscopy and X-crystallographic analyses. Experimental detail will be discussed. |
| E-mail |
yjkim@kangnung.ac.kr |
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123rd General Meeting of the KCS