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| Type |
Symposium |
| Area |
Current Trends in Organic Chemistry Ⅰ: Synthetic Methodology and Application |
| Room No. |
Room 301+302 |
| Time |
THU 17:35-18:00 |
| Code |
ORGN1-5 |
| Subject |
Copper-Catalyzed Tandem C–B and C–C Bond Formation for Asymmetric Synthesis of Organoboron Compounds |
| Authors |
Jaesook Yun
Department of Chemistry, Sungkyunkwan University, Korea |
| Abstract |
Development of efficient synthetic methods of organoboron compounds has attracted significant attention over the years due to their versatility in organic synthesis. We previously reported that a copper(I)-boryl complex coordinated with chelating bisphosphines reacted with vinyl arenes regio- and enantioselectively to form a chiral benzyl organocopper intermediate. The organocopper species was subsequently consumed in a tandem catalytic cycle for further C-C bond formation such as allylation. In this seminar, I will present our recent progress in asymmetric tandem reactions using organocopper species generated by in-situ borylcupration. |
| E-mail |
jaesook@skku.edu |
123rd General Meeting of the KCS