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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 18일 (목요일) 11:00~12:30 |
| Code |
INOR.P-33 |
| Subject |
Chiral Zinc(II) Cyclodimers: Enantio-recognition via Pulse Voltammetry
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| Authors |
Sarada Ganguri, Ahreum Kim, Ok-Sang Jung*
Department of Chemistry, Pusan National University, Korea
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| Abstract |
Self-assembly of a series of ZnX2 (X- = Cl-, Br-, and I-) with (S)-(1-isonicotinoylpyrrolidin-2-yl)methyl isonicotinate (L) as a new chiral hemicircular bidentate ligand yields a system comprising 30-membered metallacyclodimeric species [ZnX2 L] 2 with two chiral centers. In the solid state, the metallacyclodimers’ packing arrays differ according to the anions and nestled solvate molecules. In the present study, the differential pulse voltammetry (DPV) technique was employed for chiral discrimination of amino acid enantiomers with S-chiral [ZnX2 L] 2 and was found to be an effective tool for enantio-recognition of amino acids.
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| E-mail |
saradainsrik@gmail.com |
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123rd General Meeting of the KCS