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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 18일 (목요일) 11:00~12:30 |
| Code |
INOR.P-34 |
| Subject |
Confinement Effect of Palladium(II) cages on Oxidation via Pd2L4 Prolate Spheroid |
| Authors |
SeongHyeon Park, Jeyoung Lee, Ok-Sang Jung1,*
Chemistry, Pusan National University, Korea
1Department of Chemistry, Pusan National University, Korea
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| Abstract |
Self-assembly of PdX2 (X- = NO3-, BF4-, and CF3SO3-) with 2,6-bis(4′-nicotinamidephenoxy)naphthalene (L) forms a series of [Pd2L4]X4 prolate spheroids. The O donors of two Me2SO molecules within the prolate spheroid cage are oriented toward Pd(II) metal centers. In the presence of H2O2, the nestled Me2SO within cage is efficiently oxidized to Me2SO2 at room temperature.
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| E-mail |
dkdlel7964@gmail.com |
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123rd General Meeting of the KCS