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| Type |
Poster Presentation |
| Area |
Polymer Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 19일 (금요일) 11:00~12:30 |
| Code |
POLY.P-27 |
| Subject |
Hyper-Cross-Linked Polymer with Enhanced Porosity by in situ Removal of Functional Groups |
| Authors |
Jeonghyeon Lee, Myungeun Seo1,*
Graduate School of Nanoscience and Technology, Korea Advanced Institute of Science and Technology, Korea
1Graduate School of NanoScience and Technology, Korea Advanced Institute of Science and Technology, Korea
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| Abstract |
Hyper-cross-linked polymers (HCPs) contains micropores (pore size < 2 nm) within a densely cross-linked aromatic framework. For example, Lewis acid-catalyzed electrophilic aromatic substitution (i.e., hyper-cross-linking reaction) between the aromatic rings in poly(4-vinylbenzylchloride-co-divinylbenzene) (P(VBzCl-co-DVB)) arrests free volume into permanent microporosity with high specific surface area. To control the pore characteristic of HCPs, we recently reported a unique methodology based on incorporation of a trimethylsilyl (TMS) group into P(VBzCl-co-DVB). The in situ removal of the bulky TMS groups during the hyper-cross-linking reaction results in the enhanced porosity. Herein, we explore various functional groups as molecular templates to micropore creation in the HCP. By synthesizing functional group-containing styrenic monomers and hyper-cross-linking the functional-group containing precursors, we will present influence of the functional groups on the pore characteristics. |
| E-mail |
jeonghyeon@kaist.ac.kr |
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123rd General Meeting of the KCS