123rd General Meeting of the KCS

Type Oral Presentation
Area Oral Presentation for Young Polymer Scientists
Room No. Room 403
Time THU 10:00-10:12
Code POLY.O-6
Subject Structural Modification of Sulfur-based Polymer for Broad Application
Authors Jaeil Park, Myung-Han Yoon*
Division of Advanced Materials Engineering, Gwangju Institute of Science and Technology, Korea
Abstract It is well known that elemental sulfur is the promising material for upcoming generation. Although various methods such as physical or chemical modification were developed to use elemental sulfur, limited structure was reported. In this research, poly (sulfur-r-1,3 Diisoprophenylbenzene) was synthesized via inverse vulcanization in solvent. LDI-ToF was used to measure molecular weight and the number of residual double bond were calculated using 1H-NMR and EA. Average molecular weight is about 1200 g/mol and 0.5 double bonds per molecule remain unreacted. Through this functional group, photo-patterning was demonstrated by irradiating UV lamp (415 nm) for 20 min. Furthermore, copolymerization with another (meth)acrylate monomer was carried out by using P(S-DIB) as a macro chain transfer agent. It is expected that structural modification extends applicable field of the sulfur-based polymer.
E-mail jipark7704@gmail.com