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|
| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Exhibition Hall 2 |
| Time |
4월 19일 (금요일) 11:00~12:30 |
| Code |
MAT.P-468 |
| Subject |
Preparation and use of heterogeneous catalyst for olefin oxidation based on porous organic polymer support |
| Authors |
Jongho Yoon, Suk Joong Lee*
Department of Chemistry, Korea University, Korea
|
| Abstract |
As the demand for various chemicals or polymers increases, the formation of carbon–oxygen bonds became one of the most critical process, and epoxide synthesis via olefin oxidation has become important. Because widespread olefin oxidation method using toxic reagents such as peracids inevitably produces explosive and toxic by-products, researchers have been focused on using transition metal catalysts such as vanadium, manganese, iron, and copper. These transition metal-based catalysts have high selectivity and efficiency, but their low stability and separation are still challenge. So, we synthesised bispyridine based POPs and immobilized of a CuCl2 to prepare heterogeneous Cu-bpy catalyst for olefin oxidation. And it demonstrated great olefin oxidation as well as many advantages of easy separation, recycle possibility and high stability.
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| E-mail |
yoonjongho@naver.com |
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123rd General Meeting of the KCS