123rd General Meeting of the KCS

Type Poster Presentation
Area Polymer Chemistry
Room No. Exhibition Hall 2
Time 4월 19일 (금요일) 11:00~12:30
Code POLY.P-39
Subject High Density Polyethylene Production by Chromium Complex Based on a Sterically Demanding Ligand
Authors Ho Kyun Ryu, Dae Young Bae1, Eunsung Lee1,*, Kyung-sun Son*
Department of Chemistry, Chungnam National University, Korea
1Department of Chemistry, Pohang University of Science and Technology, Korea
Abstract In this presentation, a chromium complex supported by a highly sterically demanding amino triphenolate ligand is successfully prepared and investigated for ethylene polymerization. Upon activation with aluminum cocatalyst, the complex produces high density polyethylene with high melting temparture and high crystallinity. The catalytic behavior for polymerization was strongly affected by reaction solvent and the type of aluminum cocatalyst.
E-mail pkcow2@naver.com