초록문의 abstract@kcsnet.or.kr

결제문의 member@kcsnet.or.kr

현재 가능한 작업은 아래와 같습니다.
  • 09월 05일 23시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제128회 대한화학회 학술발표회, 총회 및 기기전시회 Enhance Performance in Eco-Friendly Colloidal Nanocrystal-based Photovoltaics through Ligand Modification and Architecture Engineering

2021년 8월 13일 14시 59분 00초
MAT.P-328 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
10월 14일 (목요일) 11:00~12:30
Material Chemistry
저자 및
Sung Yong Bae, Hyosung Choi1,*
Chemistry, Hanyang University, Korea
1Department of Chemistry, Hanyang University, Korea
Despite recent advances in lead-free colloidal nanocrystals (NCs) silver bismuth sulfide (AgBiS2) have demonstrated promising aspects as Eco-friendly photoactive layer in photovoltaics (PVs). The conventional halide-treated NCs provide insufficient defect passivation and poor morphology, still limiting its renaissance. Herein, we revisit the surface chemistry of the AgBiS2 NCs treated with a variety of organic ligands and reveal that reactive amines and thiols significantly deform the surface by exfoliating metal ions, making the surface prone to ambient oxidation. In contrast, electron-withdrawing carboxylic acid of 3-mercaptopropionic acid (MPA) alleviate the reactivity of thiol, providing better surface passivation without detrimental effects. Nevertheless, insufficient electronic coupling over the NCs originating from spatial separation still inhibits electric conductivity, responsible for poor performance of the NCPVs. To deploy the advantages without adverse effects, a bi-layered NC photoactive layer with a combination of existing halide-passivated NC and an organic-passivated NC provides synergistic effect in the PV performance, attributed to a construction of cascade energetic landscape that extending depletion region and improved defect passivation. Consequently, by using 3-mercaptopropionic acid (MPA), a power conversion efficiency of 6.39% in AgBiS2 NC-based PV is demonstrated, responsible for the concurrent suppression of charge recombination and enhancement in charge extraction.