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학술발표회초록보기

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  • 03월 02일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제109회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Preparation and X-ray Structure of Supramolecules Obtained from Macrocyclic Complex Having Carboxyl Side Chain at Different Reaction Condition

등록일
2012년 2월 14일 16시 47분 05초
접수번호
0308
발표코드
INOR.P-150 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
4월 25일 (수요일) 18:00~21:00
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
이재명, 곽지훈
순천대학교 화학과, Korea
The strategy for design and construction of the self-assembly structure with polyazamacrocyclic complex has been focused on tuning two-axial sites of the complexes with different auxiliary ligands. Also, the combination of coordination and hydrogen bonding approach has provided particularly interesting supramolecular systems in metal-organic hybrids. Recently, we have explored the development of a building block containing potentially coordination and hydrogen bonding sites as well to evaluate the role of coordination and hydrogen bonding in self-assembly of tetraaza donor macrocyclic complex. Here, we present the preparation and X-ray structure of two products from the reaction of macrocyclic complex of copper(II) containing carboxylic acids as side chain and tetracyanonickelate(II).at different reaction condition. We will discuss the effect of pH etc. on the crystal structure and assembly pattern of the obtained supramolecule.

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