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학술발표회초록보기

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  • 03월 02일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제109회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Metalloporphyrin Based Hexagonal MOF Particles and Their Use in Styrene Oxidation

등록일
2012년 2월 14일 20시 59분 59초
접수번호
0351
발표코드
INOR.P-153 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
4월 25일 (수요일) 18:00~21:00
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
김선돌, 이다희, 이영선, 이석중
고려대학교 화학과, Korea
Nano- and micro-sized porous coordination polymers have received a great attention owing to their potential applications in catalysis, gas storage, optics, separation and recognition. They are often showed highly ordered crystalline features with well-defined porous networks that drive enormous fundamental structural and functional interests. Metalloporphyrins are excellent building blocks for the construction of coordination polymers. They can be readily synthesized and modified with metal ions of different oxidation states and coordination preferences in their core, leading to incorporate various properties. Therefore, the preparation of porphyrin-based MOFs has been widely reported in latest years. Their properties are based on inherent characteristics of the size, morphology, and composition based on the organic building blocks. In here, we like to demonstrate the preparation of nano and micro-crystalline coordination polymer particles based on sever metalloporphyrins. Then we controlled morphology and size from different reaction conditions such as solvent, reaction temperature and reaction time. In addition, we like to demonstrate their ability as heterogeneous catalysts.

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