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학술발표회초록보기

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  • 03월 02일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제109회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Synthesis and Catalytic Activity of a Rhodium Complex for the Conversion of NAD+ to NADH

등록일
2012년 2월 16일 15시 36분 11초
접수번호
1068
발표코드
INOR.P-232 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
4월 25일 (수요일) 18:00~21:00
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
D.Sivanesan, 윤성호1
국민대학교, Korea
1국민대학교 생명나노화학과, Korea

The regeneration of the co-enzyme 1,4-NADH, the reduced form of nicotinamide adenine dinucleotide (NAD+), has continued to be high in the field of biocatalysis, where enzymatic reduction reactions are important for the synthesis of chiral organic compounds. The rhodium complexes are known for their conversion of NAD+ to NADH by the chemical and the electrochemical method. Addition to the regeneration of co-enzyme, recently it has been reported that rhodium complexes can act as an electrocatalyst for the CO2 reduction in an aqueous organic medium. To improve the catalytic properties of reported catalyst including the turn over number, the new rhodium complex was synthesized. Herein, we report the synthesis, electrochemical properties and catalytic effect of rhodium complex. Acknowledgement: This research was supported by the Converging Research Center program through the National research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (No. 2010K001153).


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