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학술발표회초록보기

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  • 09월 04일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제114회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Synthesis of Unsymmetrical Biary Ketones Using Continuous Flow Microreactor [우수포스터상]

등록일
2014년 8월 28일 14시 04분 06초
접수번호
0941
발표코드
ORGN.P-828 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
10월 15일 (수요일) 16:00~19:00
발표형식
포스터
발표분야
유기화학
저자 및
공동저자
문수연, 김원석*
이화여자대학교 화학 나노과학과, Korea

In recent years, continuous flow microreactor have been recognized as powerful tools for chemical synthesis from the viewpoint of both academia and industry due to the advantages, such as (1) controlled heat transfer, (2) controlled mixing (both fast and slow) (3) increased solution-solid phase interactions (4) controlled use of high reactive materials, and (5) tailor-made reactor to run serial reactions. Unsymmetrical Ketones are useful compounds present in many area, including materials, fragrances, and natural product synthesis. Thus, a variety of methods for the preparation of ketones have been developed. However, to the best of our knowledge, direct addition of lithium species to acyl chlorides without any additives has not yet been reported using batch reactor. Herein we report a new synthetic method for the synthesis of unsymmetrical ketones employing flow microreactor in the presence of acyl chlorides and in situ generated lithium species.


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