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114th General Meeting of Korean Chemical Society Copper-Catalyzed Wittig Olefination Using Thiols

Submission Date :
8 / 28 / 2014 , 14 : 47 : 07
Abstract Number :
114082810158
Presenting Type:
Poster Presentation
Presenting Area :
유기화학
Authors :
이찬, 장혜영1,*
아주대학교 에너지시스템학부 응용화학과, Korea
1아주대학교 화학과, Korea
Assigned Code :
ORGN.P-840 Assigend Code Guideline
Presenting Time :
10월 15일 (수요일) 16:00~19:00
In our previous study, the oxidation of thiol by using copper catalyst to form thioaldehyde as an intermediate has been proved by the mechanism study. Based on this results, the copper-catalyzed wittig olefination using thiols was proposed. And various thiols and wittig reagents reacted under aerobic conditions to provide olefins in good yield.