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114th General Meeting of Korean Chemical Society Hydrotrifluoromethylation and iodotrifluoromethylation of alkenes and alkynes using an inorganic electride as a radical generator [동우화인켐㈜ 포스터상]

Submission Date :
8 / 28 / 2014 , 15 : 28 : 44
Abstract Number :
114082810958
Presenting Type:
Poster Presentation
Presenting Area :
유기화학
Authors :
최성규, 조은진*
한양대학교 응용화학과, Korea
Assigned Code :
ORGN.P-849 Assigend Code Guideline
Presenting Time :
10월 15일 (수요일) 16:00~19:00

We describe a simple, efficient, and environmentally benign strategy for the hydrotrifluoromethylation of unactivated alkenes and alkynes through a radical-mediated reaction using an inorganic electride, [Ca2N]+·e-, as the electron source. In the transformation, anionic electrons are transferred from [Ca2N]+·e- electrides to the trifluoromethylating reagent CF3I to initiate radical-mediated trifluoromethylation. This methodology, without need for a transition-metal catalyst, allows access to diverse hydrotrifluoromethylated and iodotrifluoromethylated products in a short reaction time. In addition, iodotrifluoromethylation of alkynes proceeds selectively upon the control of electride amount.