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제114회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Synthesis and Structure of New 1D-chain Cu Complex

등록일
2014년 8월 28일 15시 38분 10초
접수번호
1110
발표코드
INOR.P-234 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
10월 15일 (수요일) 16:00~19:00
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
KhanMohammadSherjeelJaved, shuranjan sarkar1, 이주은2, 조장훈2, 이홍인2,*
경북대학교 화학과, Pakistan
1경북대학교 화학과, Bangladesh
2경북대학교 화학과, Korea
Tetrathiafulvalene (TTF) and its derivatives are renowned organic π donors which have been largely studied for distinct applications, in particular, in the area of conducting organic materials including intermolecular charge-transfer interactions with several π -accepting molecules (A). An array of mono- or polydentate coordinating functional groups has been adhered to the TTF moiety and the interrelated metal complexes have been divulged. Tetrathiafulvalene (TTF) has proven to be an excellent electron donor in the preparation of highly conductive charge transfer compounds. The structural and electronic properties of TTF are considered to be important determinants of electrical-transport properties in crystals of conductive materials. Transition metal complexes are very helpful in the synthesis of charge transfer compounds because of change in their oxidation states by the adaptation of the chemical environments around the metal ions. In this study, we have done the synthesis of the transition metal coordination polymer containing a tetrathiafulvalene (TTF) moiety substituted with a dicarboxylic group of the formula [CuL] BCDT-TTF ( L = 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hezaazacyclotetradecane) ( BCDT = Bis(4,5-carboxy-1,3-dithiolidene). It has been characterized by various analytical methods.

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