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학술발표회초록보기

초록문의 abstract@kcsnet.or.kr

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  • 09월 01일 18시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제118회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Energy Dependent Tandem Mass Spectrometry Analysis for Structural Identification of Polycyclic Aromatic Hydrocarbons

등록일
2016년 8월 24일 15시 18분 02초
접수번호
3017
발표코드
ANAL1.O-23 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
목 10시 : 53분
발표형식
구두발표
발표분야
분석화학 - Oral Presentation of Young Analytical Chemists Ⅰ
저자 및
공동저자
하지현, 김성환*
경북대학교 화학과, Korea
PAH (Polycyclic Aromatic Hydrocarbon) compound are common molecules found in the environment as well as Crude Oil. Some PAH are significant pollution source in the human body or the environment. In addition, PAHs include several isomers. It is important to analyze PAH compounds including structural isomers. One of the most widely used methods for PAH compounds is Liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). However, only a few publications reporting high resolution MS/MS spectra of PAHs are currently available. In addition, further limited number of publication is available focused on energy dependent MS/MS spectra of PAHs. In this study, it is hypothesized that obtaining MS/MS spectra with different collision energies and comparing the energy dependent pattern can be a useful tool to distinguish PAH isomers. To test the hypothesis, MS/MS spectra of 50 PAH compounds were obtained at various collisional energy and fragmentation patterns of PAHs depending on collisional energy were compared. Our results show that PAH isomers could be successfully distinguished from their significantly different relative ion intensity in the spectra obtained with various collision energies.

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