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  • 02월 22일 16시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

Enantiomeric Resolution of 1,2-Amino Alcohols by Simple Extractions Combining Stereoselective Thermodynamic and Kinetic Processes

등록일
2008년 2월 12일 11시 04분 23초
접수번호
0857
발표코드
32P163포 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
금 <발표Ⅴ>
발표형식
포스터
발표분야
유기화학
저자 및
공동저자
최수정, RajuNandhakumar1, 박현정, 정혜인, 김관묵1
이화여자대학교 나노과학부,
1이화여자대학교 화학과,
Enantiomeric recognition of aminoalcohols has been extensively studied because of their importance as biologically active molecules and ligands for stereoselective catalysts. The separation of enantiomers by reactive extraction is an industrially attractive choice as it appears to be the most cost-effective process. Versatile enantioselective extractants were tested by Kuipers et al. for chiral separation of a number of chemically related aminoalcohols by reactive extraction. The chiral extractor that has better selectivity and can be easily prepared is under need for commercial application. One such extractor is designed, synthesized and applied for enantiomeric recognition and resolution of aminoalcohols by an elegant bi-phasic extraction procedure, which is controlled by the pH conditions. The synthesis, characterization and the resolution of aminoalcohol will be presented.

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