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New Synthetic Routes to a Disulfido Dinickel(II) Complex

Submission Date :
2 / 12 / 2008 , 11 : 07 : 54
Abstract Number :
101021208678
Presenting Type:
Poster Presentation
Presenting Area :
무기화학
Authors :
조재흥, Katherine M. Van Heuvelen1, Glenn. P. A. Yap2, Thomas C. Brunold1, Charles G. Riordan2
이화여자대학교 나노과학부,
1University of Wisconsin-Madison, U.S.A.,
2University of Delaware, U.S.A.,
Assigned Code :
28P100포 Assigend Code Guideline
Presenting Time :
금 <발표Ⅲ>

The activation of dioxygen by monovalent nickel complexes has proven to be a productive approach to the generation of new, metastable Ni-Ox species that include side-on and end-on superoxo and trans-μ-1,2-peroxo motifs. Recently, we have turned our attention to the heavier congener sulfur. Herein, we report the structural and spectroscopic characterization of a μ-η22-disulfido dinickel(II) complex, [(PhTttBu)Ni]2(μ-η22-S2), prepared by following either of two synthetic routes: (i) reaction of S8 with the nickel(I) complex [PhTttBu]Ni(CO) or (ii) the thermal decomposition of the nickel(II) complex [PhTttBu]Ni(SCPh3) via C-S bond cleavage.